I need to call a batch file from a VBScript and provide
variables to it like:

Call "%0\..\addhome.bat " & UserName & " " & FileLocation

It doesn't seem to like this however.

Alternatively, what I'd really like to do is be able to
process through an entire OU of users and create shares
and set permissions for them from within the VBScript.  I
can process the users but don't know how to create the
share and set the permissions.  That's what I was going to
use the batch file for(above).

http://www.infinitemonkeys.ws/infinitemonkeys/articles/asp/950h.asp

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Dim Shell
Set Shell = CreateObject("Wscript.Shell")
Shell.Run "%0\..Anything.bat" & %USERNAME% & FileLocation

see if that helps